ASTM E1559 Contamination Outgassing Characteristics of Spacecraft Materials

    What is ASTM E1559? 

    ASTM E1559 is a standard test method for evaluating spacecraft materials for contamination outgassing characteristics to assess their quality and durability. In this test method, a specimen is placed in an effusion cell under vacuum, and the mass deposited onto a quartz crystal microbalance at various fixed collector temperatures is measured with high sensitivity. This technique measures the total mass flux a material evolves in vacuum when exposed to vacuum, as well as the rate at which that mass flux deposits onto surfaces at different temperatures. ASTM E1559 (Standard Test Method for Contamination Outgassing Characteristics of Spacecraft Materials) applies to temperatures from 298 K to 398 K and to outgassing external pressures below 7 × 10⁻³ Pa. Engineers use the resulting kinetic data to build mathematical models that predict molecular contaminant generation, migration, and deposition. 

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    Get Certified ASTM E1559 Testing for Reliable Spacecraft Material Qualification

    Certification confirms that spacecraft materials meet the relevant ASTM E1559 requirements for acceptable outgassing kinetics and deposition behavior in a vacuum environment. ASTM E1559 certified testing measures a material’s molecular contamination potential before mission engineers accept it for use near optical or sensor-critical spacecraft components. Testing and certification verify compliance with ASTM E1559 requirements and minimize mission failures due to contamination. 

    What is the Scope of ASTM E1559? 

    ASTM E1559 is a test method used to measure data for characterization of the outgassing kinetics of product release from spacecraft materials. It measures total mass flux and deposition rate on a collector surface in a vacuum effusion cell system. This standard offers a uniform test method to measure the migration and deposition of molecular contamination under vacuum and temperature conditions on quartz crystal microbalances.

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    The main objective of ASTM E1559 is to measure how quickly the materials given in spacecraft can outgas in a controlled vacuum environment. It is employed in industries for material selection, contamination control, and mission-critical optical and sensor protection. The scope of ASTM E1559 includes-

    • Material: Organic, polymeric, and inorganic spacecraft materials such as potting compounds, foams, elastomers, films, adhesives, coatings, fabrics, and lubricants.
    • Purpose: Quantification for evaluation of outgassing kinetics and molecular contamination.
    • Property measured: Total mass flux, deposition rate, and collected volatile condensable material.
    • Method: The test involves heating the specimen under vacuum in an effusion cell. Quartz crystal microbalances held at specified collector temperatures measure the deposited mass.
    • Result: Mass flux and deposition rate are measured in nanograms per square centimeter.
    • Test Limitations: It applies to specimen temperatures from 298 K to 398 K, and the test pressure is less than 7×10-3 Pa.
    • Environmental conditions: Specimen temperature and collector temperature significantly affect deposition rate and contamination behavior.
    • Applications: Satellite component qualification, optical and sensor contamination control, spacecraft material selection, mission reliability assurance.

    What are the Uses of ASTM E1559 Testing?

    ASTM E1559 testing helps evaluate the molecular contamination behavior of spacecraft materials in vacuum. Engineers then use the results to compare materials and to find out how well materials prevent contaminants from landing on sensitive spacecraft surfaces. This standard-

    • Determines outgassing rates of spacecraft materials.
    • Simulates vacuum exposure by using a controlled effusion cell system.
    • Evaluates the deposition behavior on surfaces with different collector temperatures.
    • Helps to support mathematical models for contaminant migration prediction.
    • Helps to compare materials for spacecraft applications.
    • Helps to keep optical lenses and sensors free from contamination.
    • Supports the selection of materials for mission-critical parts of spacecraft. 

    What Materials Can Be Tested Under ASTM E1559? 

    ASTM E1559 is used to test the low outgassing properties of adhesives, coatings, polymers, lubricants and composites in spacecraft construction that meet stringent material requirements in vacuum and high radiation environments. A sample size, which is large enough to expose a representative surface area within the effusion cell, is selected by the analysts.

    Why is ASTM E1559 Important? 

    ASTM E1559 is important for ensuring that spacecraft and other systems function reliably and perform, providing a standardized method of assessment of material outgassing and preventing mission-critical failures. Mission engineers use these measured kinetics to protect optical lenses, sensors, and other contamination-sensitive equipment from performance degradation during a mission. 

    ASTM E1559 Equipment and Sample Preparation Guide

    ASTM E1559 is designed to measure outgassing kinetics with a vacuum effusion cell and quartz crystal microbalance system. The amount of material to be placed in the effusion cell is chosen according to the effusion cell geometry. The standard also includes two test methods: Method A (standard specimen and collector temperature) and Method B (user-defined temperatures).

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    Sample and Specimen DetailsTechnicians test representative samples of organic, polymeric, and inorganic spacecraft materials, prepared for controlled vacuum outgassing measurement. 
    Specimen PreparationTechnicians weigh, identify, and load the specimen into the effusion cell, and they record its initial mass and condition before testing begins. 
    Specimen DimensionsTechnicians size the specimen to fit the effusion cell geometry, using a quantity sufficient to expose a representative outgassing surface area 
    InstrumentationVacuum chamber, effusion cell, temperature control system, quartz crystal microbalances, and a data acquisition system. 

    Testing Procedures and Requirements for ASTM E1559  

    A technician places the specimen in the effusion cell, pumps the chamber to the required pressure, and then heats the specimen to the desired temperature. Quartz crystal microbalances positioned at various collector temperatures record the deposited mass over the exposure period. ASTM E595 is another related, less complex screening test that quantifies total mass loss and the volatile condensable material collected under a single point bake-out procedure. 

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    Chamber Evacuation Technicians evacuate the vacuum chamber to a pressure below 7 × 10⁻³ Pa before beginning the heating cycle. 
    Specimen Heating Technicians heat the specimen in the effusion cell to a controlled temperature between 298 K and 398 K. 
    Deposition Monitoring The quartz crystal microbalances continuously record deposited mass at their specified collector temperatures throughout the exposure period. 
    Thermal Desorption Analysis  Technicians optionally heat the QCM crystals post-test to generate desorption profiles and identify specific contaminant compounds.  
    Data Processing Analysts process the recorded deposition data to calculate total mass flux and deposition rate as functions of time and temperature. 

    ASTM E1559 Testing Process and Data Collection

    Testing starts after the specimen is weighed and placed into the effusion cell, and the vacuum chamber is pumped to the desired pressure. The temperature control system then raises the temperature of the specimen to the desired temperature, while the chamber holds the vacuum conditions. The quartz crystal microbalances located at their assigned collector temperatures continuously measure the amount of mass deposited as the outgassing products move from the specimen. The data acquisition system records the deposition reading during the exposure period. Finally, the analyst analyzes the data recorded to determine the mass flux and deposition rate as a function of time and temperature. 

    The image shows a spacecraft material specimen loaded into a vacuum effusion cell with quartz crystal microbalances positioned to measure outgassing deposition.
    ASTM E1559 Vacuum Outgassing Testing of a Spacecraft Material Specimen

    Common Challenges and Troubleshooting

    The difficulties of testing are maintaining vacuum, detecting volatile substances, and guaranteeing substrate precision. Troubleshooting includes recalibrating pumps, cleaning the sample holders, and checking sensor alignment. It is crucial to ensure accurate results to the right standards. Laboratories overcome these issues by measuring the vacuums in the chambers, adjusting the temperature controls for the collectors, and conditioning the specimens prior to their testing under controlled storage conditions.

    ASTM E1559 Analysis Results and Interpretation

    The laboratory supplies the measured outgassing rate of the specimen of a spacecraft material. ASTM E1559 deals with the overall mass flux and deposition rate, rather than a general overall material-performance rating.

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    • The total mass flux and deposition rate are reported by the laboratory, both as a function of time and collector temperature.
    • The technician documents the material condition tested, such as the type of specimen and the preconditioning history.
    • The analyst takes measurements of the deposition data under the given vacuum and temperature conditions, and correlates the data with the material being tested and the material’s composition.
    • The engineer considers factors such as specimen temperature, collector temperature, and exposure duration when interpreting outgassing results for mission applications.
    • Engineers use the measured outgassing kinetics to support contamination modeling and material selection for spacecraft components. 

    Link to ASTM E1559 

    FAQ

    How does ASTM E1559 differ from ASTM E595 outgassing testing?
    There are two test methods: ASTM E1559 details the outgassing kinetics (deposition rate with time and collector temperature), and ASTM E595 offers a simplified, single-point bake-out screening test for total mass loss and collected volatile condensable material.
    Test Method A provides standard temperatures for the specimen and collector for comparison between materials, and Test Method B provides user-specified temperatures to match the temperature conditions of a given mission.
    Collector temperature strongly influences how much outgassed material condenses on a given surface, so testing at multiple collector temperatures helps engineers predict contamination risk for spacecraft components operating at different thermal conditions.

    Updated on September 11, 2026

    Rohit Dhembare
    About Author
    Rohit Dhembare is an Operations Associate at Matestlab Inc., holds a postgraduate degree in Organic Chemistry and is trained in Materials Science testing techniques.
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