A high-pressure differential scanning calorimetry (DPSC) test is one of the standard methods used to determine the oxidative induction time of polyolefin geosynthetics. It is used to measure the durability of compounded polyolefins to oxidative degradation under high oxygen pressure at a controlled temperature. This standard provides a test method for determining antioxidant stabilization using a pressure differential scanning calorimeter (PDSC) under accelerated oxidative conditions. The primary purpose of ASTM D5885 is to determine the oxidative induction time of a polyolefin geosynthetic as a control method of antioxidant stabilization.
The scope of ASTM D5885 includes:
- Material type: Polyolefin geosynthetics such as geomembranes, geogrids, geonets, and geotextiles.Â
- Purpose: The purpose is to quantify for the evaluation of oxidative induction time and antioxidant stabilization.Â
- Properties evaluated: Oxidative induction time (OIT).Â
- Testing Method: Testing involves pressurizing a specimen disk in an oxygen-filled D.S.C. cell and heating to the isothermal test condition.Â
- Result: The oxidative induction time is reported in minutes at the specified test temperature and pressure.Â
- Test Limitations: he test standard is applicable to materials with an OIT > 30 minutes when tested at 3.4 MPa of oxygen at 150°C, and the results do not directly reflect the service life of a geomembrane.Â
- Use conditions: Oxygen pressure and isothermal test temperature significantly affect the measured oxidative induction time.Â
- Applications: Landfill liner and containment system quality control, geomembrane formulation comparison, geosynthetic supplier verification, antioxidant stabilization monitoring.Â
What are the Uses of ASTM D5885 Testing?
ASTM D5885 testing is used to evaluate the antioxidant stabilization of polyolefin geosynthetic materials when exposed to accelerated oxidative conditions. Engineers use the results to compare formulations and to understand the oxidative resistance of a geosynthetic. This standard-
- Assesses the oxidative induction time of polyolefin geosynthetics.
- Enhances oxidative degradation artificially by increasing the pressure of oxygen.
- Assesses antioxidant stabilization as received from a supplier.
- Helps to compare the various geomembrane formulations at a given test temperature.
- Aids in quality control monitoring of geosynthetic stabilization.
- Assists in product development and formulation verification.
- Helps in the selection of antioxidant packages for geosynthetic products.
What Materials Can Be Tested Under ASTM D5885?
ASTM D5885 is used for polyolefin geosynthetics such as geomembranes, geogrids, geonets, and geotextiles, and is most commonly used for geomembranes. Common materials are geomembranes for landfill liners and polymembranes for containment applications, e.g., polyethylene, polypropylene. Analysts select a small specimen disc cut from the geosynthetic sample for testing.
Why is ASTM D5885 Important?
ASTM D5885 is a standard, accelerated method to determine the antioxidant stabilization added to a geosynthetic made from a polyolefin. Manufacturers and/or specifiers use this measured oxidative induction time as a quality control measurement, but the standard clarifies that the OIT value should not be used to predict the geomembrane’s actual service life.