ASTM D2863 Minimum Oxygen Concentration to Support Candle-Like Combustion of Plastics (Oxygen Index)

    What is ASTM D2863?

    ASTM D2863 describes a standard test method for measuring the minimum oxygen concentration in an oxygen–nitrogen atmosphere that supports candle-like combustion of plastic materials. The test measures the oxygen index of a vertically mounted plastic test specimen when exposed to a controlled gas mixture and examines how the test specimen burns. ASTM D2863 (Standard Test Method for Measuring the Minimum Oxygen Concentration to Support Candle-Like Combustion of Plastics (Oxygen Index)) helps engineers and technicians compare the relative flammability characteristics of plastics under specific laboratory conditions. The minimum oxygen concentration that just supports flaming combustion is expressed as a percent volume. 

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    The ASTM D2863 standard comprises three test procedures A, B, and C, involving top surface ignition, propagating ignition, and the comparison with a specified minimum value of the oxygen index. The measured oxygen concentration can be used for material comparison, development, and quality control. However, the oxygen index result does not directly reflect actual fire performance under use conditions or predict performance in a specific fire environment.

    Get Certified ASTM D2863 Testing for Reliable Oxygen Index Evaluation

    The combustion behavior of plastic materials can differ based on the plastic’s composition and the environment in which combustion occurs. Thus, oxygen index testing helps assess the comparative combustibility of plastics under defined conditions. The ASTM D2863 standard specifies a method for determining the minimum concentration of oxygen below which candle-like combustion will not sustain. Results can support material development, quality control, and comparisons of plastic formulations.

    What is the Scope of the ASTM D2863 Test Standard?

    This standard determines the minimum oxygen concentration in an oxygen-nitrogen mixture that supports candle-like combustion of plastic specimens under specified conditions. The ASTM D2863 standard-

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    • Measures the Oxygen Index of plastics.
    • Determines the lowest oxygen level that will permit combustion.
    • Assesses the burning behavior of the candle.
    • Works with mixtures of controlled oxygen and nitrogen gas.
    • Tests plastic specimens that are mounted vertically.
    • Facilitates the comparison of plastic materials.
    • Assists in the assessment of combustion characteristics relative to each other.
    • Assists in material creation and quality control.

    What are the Uses of ASTM D2863 Testing?

    ASTM D2863 testing helps laboratories determine the amount of oxygen needed to keep plastic material burning. Engineers use the results to compare formulations and characterize combustion behavior in controlled laboratory conditions.  The ASTM D2863 standard-

    • Determines oxygen index.
    • Compares combustion properties.
    • Assists in comparing plastic formulations.
    • Supports material development.
    • Assists in the determination of the alteration of the composition of a material.
    • Supports quality control.
    • Provides information to research and development.
    • Contributes to the description of the combustion behavior of plastics.

    Which materials can be tested under ASTM D2863?

    ASTM D2863 is applicable to plastic materials that can be fabricated into appropriate vertical test specimens for oxygen index testing. When the specimen requirements are met, the test can assess various plastic formulations and material forms. Before setting up specimens for the test, technicians should determine the plastic type, specimen size, conditioning, and combustion characteristics.

    Why is ASTM D2863 Important?

    ASTM D2863 is a standardized procedure for measuring the oxygen required to sustain candle-like burning of plastics. Standardized testing compares materials under controlled atmospheric conditions. These results help characterize the material, develop formulations, and support quality control when evaluating the combustion behavior of plastics.

    ASTM D2863 Equipment and Sample Preparation Guide

    The ASTM D2863 standard calls for an oxygen index testing apparatus that is able to control the oxygen-nitrogen atmosphere surrounding a vertically mounted specimen. Technicians take specimens of appropriate size and condition them for testing.

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    Sample and Specimen DetailsThe operator tests representative plastic specimens suitable for vertical oxygen index testing.
    Specimen PreparationTechnicians prepare specimens with smooth, adequate surfaces and prevent contamination or damage that might alter combustion characteristics.
    Specimen DimensionsThe dimensions and geometry of the ASTM D2863 specimens vary depending on the specific requirements. Solid, laminated, or cellular materials characterized by an apparent density greater than 15 kg/m3 and structurally self-supporting specimens in the form of vertical bars or sheets up to 10.5-mm thick are used.
    InstrumentationThe testing process is performed using oxygen index apparatus, a transparent test column, oxygen and nitrogen gas supplies, a flow-control system, a specimen holder, an ignition source, and measurement equipment.

    Testing Procedures and Requirements for ASTM D2863

    The ASTM D2863 test method determines the minimum oxygen concentration in a flowing oxygen-nitrogen mixture that supports flame combustion of plastics. The upper part of the sample is burned, and the combustion behavior is observed under the oxygen concentration. This standard provides three procedures. Procedure A involves top surface ignition, Procedure B involves propagating ignition, and Procedure C involves comparison with a minimum oxygen index. The procedure outlined in ASTM D2863 is as follows-

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    Procedure AThe oxygen index is the percentage of oxygen in the mixture that supports sustained burning of a specimen. Analysts ignite the top surface of the upper end of the specimen using the igniter, and apply the flame for up to 30 s.
    Procedure BAnalysts use the igniter to produce burning across the top and partially down the vertical faces of the specimen. The oxygen index is the percentage of oxygen in the mixture that supports sustained burning of a specimen. The top surface of the upper end of the specimen is ignited using the igniter, and the flame is applied for up to 30 s.
    Procedure CAnalysts assess the burning behavior of three specimens and record the oxygen index if at least two of three are extinguished.
    Specimen PreparationTechnicians prepare and condition the plastic specimens as required prior to testing.
    Specimen InstallationThe operator places the specimen in the oxygen index test column, in a vertical position.
    Gas Mixture ControlTechnicians set the desired oxygen and nitrogen levels and control the atmosphere surrounding the specimen.
    Ignition and ObservationThe operator ignites the specimen and notes whether it burns in a candle-like fashion under the chosen oxygen concentration.
    Oxygen Index DeterminationTechnicians adjust the oxygen concentration as needed to find the lowest concentration that maintains the desired combustion behavior.
    Result ReportingLaboratories report the oxygen index value, specimen information, conditioning information, and test observations.

    ASTM D2863 Testing Process and Data Collection

    Technicians select representative plastic specimens and condition them according to requirements. They then place each specimen in the oxygen index apparatus in the upright position. The operator then sets up a controlled atmosphere of oxygen and nitrogen and introduces the ignition source to the specimen. The operator observes the combustion behavior and adjusts it according to the test procedure. Finally, the minimal oxygen concentration that allows the specified candle-like combustion behavior is calculated by the analysts. Laboratories report the oxygen index and the relevant information on the specimen and the test conditions.

    This image shows a vertically mounted plastic specimen inside an oxygen index test column during ASTM D2863 combustion testing.
    ASTM D2863 Oxygen Index Testing of Plastics

    Common Challenges and Troubleshooting

    Consistent specimen preparation, gas-flow control, ignition, and observation are essential to obtaining accurate ASTM D2863 results. Changes in specimen condition or gas concentration may affect combustion behavior and the oxygen index. Technicians should check the gas supply and flow-control systems before testing. They should also learn how to prepare specimens consistently and maintain the required test conditions during testing.

    ASTM D2863 Analysis Results and Interpretation

    The report summarizes the oxygen concentration needed to sustain candle-like combustion of the tested plastic. The oxygen index is reported along with specimen information and relevant test conditions.

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    • The test results report the oxygen index per ASTM D2863, expressed as oxygen concentration in volume percent.
    • Engineers use the oxygen index value to assess the oxygen concentration required to sustain combustion and compare the combustion characteristics of plastic materials.
    • Higher oxygen index values indicate that a higher oxygen concentration is required to sustain the specified combustion condition.
    • Engineers interpret the results as comparative combustion data and do not use oxygen index values alone to predict actual fire performance.
    • Technicians follow consistent specimen preparation and controlled gas conditions to obtain reliable and comparable results.

    Link to ASTM D2863

    Updated on August 25, 2026

    Suyog Kamble
    About Author
    Suyog Kamble is an Operations Associate at Matestlab Inc. Suyog holds a postgraduate degree in organic chemistry and is trained in material science topics.
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